高分子定性與分析

本課程之目標是讓學生可以瞭解高分子材料之分析鑑定方法,其中包括:(1)高分子之分子量鑑定方法(2)高分子之化學結構鑑定方法;例如:UV、IR、NMR、Mass等方譜(3)高分子熱性質鑑定方法;例如:DSC、TGA、TMA、DMA、DEA及TSC等(4)高分子型態學鑑定方法;例如:X-ray、SEM、TEM、AFM等及(5)高分子機械性質量測方法。

參考書目: 1. Rabek “Experimental Methods in Polymer Chemistry – Physical Principles and Applications” John Wiley and Sons, N.Y. (1980). 2. L.S. Bark and N.S. Allen “Analysis of Polymer Systems” Applied Science, London (1982). 3. E. Schroder, G. Muller and K.F. Arndt “Polymer Characterization” Hanser, Munich Vienna New York (1988). 4. D. Campbell and J.R. White “Polymer Characterization – Physical techniques” Chapman and Hall, London New York (1989). 5. H.G. Barth and J.W. Mays “Modern Method of Polymer Characterization” John Wiley and Sons, New York (1991). 6. L.C. Sawyer and D.T.Grubb “Polymer Microscopy” Chapman and Hall, London New York (1987). 7. Gunther Kampf “Charaterization of Plastics by Physical Methods” Hanser, Munich Vienna New York (1986).

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1.期中考 50% 2.期末考 50%

• Chap1. Overview of the structure and properties of polymers

  1-1 General Introduction 1-2 Stereochemistry of Polymers 1-3 Copolymer 1-4 Super Molecular Structures 1-5 Molecular Weight and Molecular Weight Distribution

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  3

• Chap2. Chemical Analysis

  2-1 Sampling 2-2 Qualitative Identification of the Elemental Nature of the polymer 2-3 Thermal Decomposition of Polymers 2-4 Summary

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  3

• Chap3. Determination of Molecular Weight and Molecular Weight Distribution

  3-1 Membrane Osmometry 3-2 Vapor Phase Osmometry 3-3 Viscometry 3-4 Light Scattering 3-5 Ultracentrifugation 3-6 Chromatography 3-7 End-group Analys

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  6

• Chap4. Ultraviolet and Visible Spectroscopy of Polymers

  4-1 Principles 4-2 Instrumentation of UV and Visible Spectroscopy 4-3 Application of UV and Visible in Polymers

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  3

• Chap5. Infrared and Raman Spectroscopy of Polymers

  5-1 Instrumentation of IR and Raman Spectroscopy 5-2 FT-IR 5-3 Experimental Techniques in FT-IR 5-4 Applications of IR and Raman in Polymers

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  3

• Chap6. Nuclear Magnetic Resonance Spectroscopy

  6-1 Instrumentation of NMR Spectroscopy 6-2 FT-NMR 6-3 13C-NMR 6-4 Solid State NMR 6-5 Applications of NMR in Polymers

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  3

• Chap7. Mass Spectroscopy and ESCA

  7-1 Instrumentation 7-2 Applications of Mass Spectroscopy to Analysis of Polymers 7-3 Applications of ESCA to Analysis of Polymers

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  3

• Chap8. Electron Microscopy

  8-1 Principles 8-2 Transmission Electron Microscopy 8-3 Scanning Electron Microscopy 8-4 Applications of Electron Microscopy in Polymer Research

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  6

• Chap9. X-Ray Diffraction Analysis

  9-1 Principles 9-2 Wide-angle X-ray Diffraction 9-3 Small-angle X-ray Diffraction 9-4 X-ray Diffractometer 9-5 Applications of X-ray in Polymer Research

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  3

• Chap10. Thermal Analysis of Polymers

  10-1 Thermal Transitions of Polymers 10-2 DSC, TGA and TMA 10-3 Application of DSC in Polymer Research

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  3

• Chap11. Electrical and Optical Properties of Polymers

  11-1 Dielectric Properties 11-2 Electronic Conductivity 11-3 Birefringence 11-4 Optical Dichroism 11-5 Optical Microscopy

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  6

• Chap12. Mechanical Properties of Polymers

  12-1 Tensile Tests 12-2 Hardness 12-3 Friction and Wear 12-4 Fracture and Fatigue Tests

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  6

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地點

田家炳光電大樓R716

時間

星期三下午14:00-17:00 / 星期四下午14:00-17:00

聯絡方式

分機:31523 email address:cshsu@mail.nctu.edu.tw