物理化學(2)

Physical Chemistry(II)

學期

113-1

學分

0 學分

當期課號

910261

永久課號

SESE20040

開課單位

系統工程與科技學士學位學程

授課教師

黃文鍵

類別

必修

上課時間表

節	週二	週五
6 14:20–15:10		物理化學(2) 2 節連堂
7 15:30–16:20		物理化學(2) 2 節連堂
A 18:30–19:20	物理化學(2)

* 根據陽明交大上課時間表所列

概述

學習基本的量子力學觀念並了解量子力學在微觀化學體系的應用,作為大四以後進階課程的基礎。

先修科目

普通化學、物理化學(1)

備註

無備註

教學方式

課堂解說、教學投影片

評分方式

平時作業(30%) 期中考(30%) 期末考(40%)

課程大綱

Introduction to Physical Chemistry

講授：

3
Electromagnetic Radiation and the Old Quantum Theory

1. Simple Harmonic Motion 2. Plane Waves and Standing Waves 3. Blackbody Radiation 4. Einstein and the Quantization of Radiation 5. Zero-Point Energy

講授：

3
Bohr's Atomic Theory

1. Spectral Series

講授：

3
The Foundations of Quantum Mechanics

1. The Wave Nature of Electrons 2. Zero-Point The Uncertainty Principle

講授：

3
Schrodinger's Wave Mechanics

1. Eigenfunctions and Normalization

講授：

3
Schrodinger's Wave Mechanics

1. Eigenfunctions and Normalization

講授：

3
Quantum-Mechanical Postulates

1. Orthogonality of Wave Functions

講授：

3
Quantum-Mechanical Postulates

1. Orthogonality of Wave Functions

講授：

3
Quantum Mehanics of Some Simple Systems

1. The Free Particle 2. The Particle in a Box 3. The Harmonic Oscillator

講授：

3
Mid-term Exam

講授：

3
Quantum Mechanics of Hydrogenlike Atoms

1. Solution of the  Equation 2. Solution of the  Equation 3. Solution of the Solution of the R Equation 4. Complete Wave Functions

講授：

3
Quantum Mechanics of Hydrogenlike Atoms

1. Solution of the  Equation 2. Solution of the  Equation 3. Solution of the Solution of the R Equation 4. Complete Wave Functions

講授：

3
Physical Significance of the Orbital Quantum Numbers

1. The Principal Quantum Number n 2. Angular Dependence of the Wave Function: The Quantum Numbers ʅ and mʅ

講授：

3
Angular Momentum and Magnetic Moment

1. Angular Momentum 2. Magnetic Moment

講授：

3
The Rigid Linear Rotor Spin Quantum Numbers

The Rigid Linear Rotor Spin Quantum Numbers

講授：

3
Many-Electron Atoms

1. The Aufbau Principle 2. The Pauli Exclusion Principle 3. Hund's Rule

講授：

3
Approximation Method in Quantum Mechanics

1. The Variation Method 2. Perturbation Method 3. Slater Orbitals 4. Relativistic Effects in Quantum Mechanics 5. Key Equations

講授：

3
Approximation Method in Quantum Mechanics

1. The Variation Method 2. Perturbation Method 3. Slater Orbitals 4. Relativistic Effects in Quantum Mechanics 5. Key Equations

講授：

3
Final Exam

講授：

3

週次計畫

週次	主題
第 1 週	Introduction to Physical Chemistry 2024-09-03(二),2024-09-06(五) 時數：[2024-09-03]黃文鍵(1.00)
第 1 週	Introduction to Physical Chemistry 2024-09-03(二),2024-09-06(五) 時數：[2024-09-06]黃文鍵(2.00)
第 2 週	Electromagnetic Radiation and the Old Quantum Theory 1. Simple Harmonic Motion 2. Plane Waves and Standing Waves 3. Blackbody Radiation 4. Einstein and the Quantization of Radiation 5. Zero-Point Energy 2024-09-10(二),2024-09-13(五) 時數：[2024-09-10]黃文鍵(1.00)
第 2 週	Electromagnetic Radiation and the Old Quantum Theory 1. Simple Harmonic Motion 2. Plane Waves and Standing Waves 3. Blackbody Radiation 4. Einstein and the Quantization of Radiation 5. Zero-Point Energy 2024-09-10(二),2024-09-13(五) 時數：[2024-09-13]黃文鍵(2.00)
第 3 週	Bohr's Atomic Theory 1. Spectral Series 2024-09-17(二),2024-09-20(五) 時數：[2024-09-17]黃文鍵(1.00)
第 3 週	Bohr's Atomic Theory 1. Spectral Series 2024-09-17(二),2024-09-20(五) 時數：[2024-09-20]黃文鍵(2.00)
第 4 週	The Foundations of Quantum Mechanics 1. The Wave Nature of Electrons 2. Zero-Point The Uncertainty Principle 2024-09-24(二),2024-09-27(五) 時數：[2024-09-24]黃文鍵(1.00)
第 4 週	The Foundations of Quantum Mechanics 1. The Wave Nature of Electrons 2. Zero-Point The Uncertainty Principle 2024-09-24(二),2024-09-27(五) 時數：[2024-09-27]黃文鍵(2.00)
第 5 週	Schrodinger's Wave Mechanics 1. Eigenfunctions and Normalization 2024-10-01(二),2024-10-04(五) 時數：[2024-10-01]黃文鍵(1.00)
第 5 週	Schrodinger's Wave Mechanics 1. Eigenfunctions and Normalization 2024-10-01(二),2024-10-04(五) 時數：[2024-10-04]黃文鍵(2.00)
第 6 週	Schrodinger's Wave Mechanics 1. Eigenfunctions and Normalization 2024-10-08(二),2024-10-11(五) 時數：[2024-10-08]黃文鍵(1.00)
第 6 週	Schrodinger's Wave Mechanics 1. Eigenfunctions and Normalization 2024-10-08(二),2024-10-11(五) 時數：[2024-10-11]黃文鍵(2.00)
第 7 週	Quantum-Mechanical Postulates 1. Orthogonality of Wave Functions 2024-10-15(二),2024-10-18(五) 時數：[2024-10-15]黃文鍵(1.00)
第 7 週	Quantum-Mechanical Postulates 1. Orthogonality of Wave Functions 2024-10-15(二),2024-10-18(五) 時數：[2024-10-18]黃文鍵(2.00)
第 8 週	Quantum-Mechanical Postulates 1. Orthogonality of Wave Functions 2024-10-22(二),2024-10-25(五) 時數：[2024-10-22]黃文鍵(1.00)
第 8 週	Quantum-Mechanical Postulates 1. Orthogonality of Wave Functions 2024-10-22(二),2024-10-25(五) 時數：[2024-10-25]黃文鍵(2.00)
第 9 週	Quantum Mehanics of Some Simple Systems 1. The Free Particle 2. The Particle in a Box 3. The Harmonic Oscillator 2024-10-29(二),2024-11-01(五) 時數：[2024-10-29]黃文鍵(1.00)
第 9 週	Quantum Mehanics of Some Simple Systems 1. The Free Particle 2. The Particle in a Box 3. The Harmonic Oscillator 2024-10-29(二),2024-11-01(五) 時數：[2024-11-01]黃文鍵(2.00)
第 10 週	Mid-term Exam 2024-11-05(二),2024-11-08(五) 時數：[2024-11-05]黃文鍵(1.00)
第 10 週	Mid-term Exam 2024-11-05(二),2024-11-08(五) 時數：[2024-11-08]黃文鍵(2.00)
第 11 週	Quantum Mechanics of Hydrogenlike Atoms 1. Solution of the  Equation 2. Solution of the  Equation 3. Solution of the Solution of the R Equation 4. Complete Wave Functions 2024-11-12(二),2024-11-15(五) 時數：[2024-11-12]黃文鍵(1.00)
第 11 週	Quantum Mechanics of Hydrogenlike Atoms 1. Solution of the  Equation 2. Solution of the  Equation 3. Solution of the Solution of the R Equation 4. Complete Wave Functions 2024-11-12(二),2024-11-15(五) 時數：[2024-11-15]黃文鍵(2.00)
第 12 週	Quantum Mechanics of Hydrogenlike Atoms 1. Solution of the  Equation 2. Solution of the  Equation 3. Solution of the Solution of the R Equation 4. Complete Wave Functions 2024-11-19(二),2024-11-22(五) 時數：[2024-11-19]黃文鍵(1.00)
第 12 週	Quantum Mechanics of Hydrogenlike Atoms 1. Solution of the  Equation 2. Solution of the  Equation 3. Solution of the Solution of the R Equation 4. Complete Wave Functions 2024-11-19(二),2024-11-22(五) 時數：[2024-11-22]黃文鍵(2.00)
第 13 週	Physical Significance of the Orbital Quantum Numbers 1. The Principal Quantum Number n 2. Angular Dependence of the Wave Function: The Quantum Numbers ʅ and mʅ 2024-11-26(二),2024-11-29(五) 時數：[2024-11-26]黃文鍵(1.00)
第 13 週	Physical Significance of the Orbital Quantum Numbers 1. The Principal Quantum Number n 2. Angular Dependence of the Wave Function: The Quantum Numbers ʅ and mʅ 2024-11-26(二),2024-11-29(五) 時數：[2024-11-29]黃文鍵(2.00)
第 14 週	Angular Momentum and Magnetic Moment 1. Angular Momentum 2. Magnetic Moment 2024-12-03(二),2024-12-06(五) 時數：[2024-12-03]黃文鍵(1.00)
第 14 週	Angular Momentum and Magnetic Moment 1. Angular Momentum 2. Magnetic Moment 2024-12-03(二),2024-12-06(五) 時數：[2024-12-06]黃文鍵(2.00)
第 15 週	The Rigid Linear Rotor Spin Quantum Numbers 2024-12-10(二),2024-12-13(五) 時數：[2024-12-10]黃文鍵(1.00)
第 15 週	The Rigid Linear Rotor Spin Quantum Numbers 2024-12-10(二),2024-12-13(五) 時數：[2024-12-13]黃文鍵(2.00)
第 16 週	Many-Electron Atoms 1. The Aufbau Principle 2. The Pauli Exclusion Principle 3. Hund's Rule 2024-12-17(二),2024-12-20(五) 時數：[2024-12-17]黃文鍵(1.00)
第 16 週	Many-Electron Atoms 1. The Aufbau Principle 2. The Pauli Exclusion Principle 3. Hund's Rule 2024-12-17(二),2024-12-20(五) 時數：[2024-12-20]黃文鍵(2.00)
第 17 週	Approximation Method in Quantum Mechanics 1. The Variation Method 2. Perturbation Method 3. Slater Orbitals 4. Relativistic Effects in Quantum Mechanics 5. Key Equations 2024-12-24(二),2024-12-27(五) 時數：[2024-12-24]黃文鍵(1.00)
第 17 週	Approximation Method in Quantum Mechanics 1. The Variation Method 2. Perturbation Method 3. Slater Orbitals 4. Relativistic Effects in Quantum Mechanics 5. Key Equations 2024-12-24(二),2024-12-27(五) 時數：[2024-12-27]黃文鍵(2.00)
第 18 週	Approximation Method in Quantum Mechanics 1. The Variation Method 2. Perturbation Method 3. Slater Orbitals 4. Relativistic Effects in Quantum Mechanics 5. Key Equations 2024-12-31(二),2025-01-03(五) 時數：[2024-12-31]黃文鍵(1.00)
第 18 週	Approximation Method in Quantum Mechanics 1. The Variation Method 2. Perturbation Method 3. Slater Orbitals 4. Relativistic Effects in Quantum Mechanics 5. Key Equations 2024-12-31(二),2025-01-03(五) 時數：[2025-01-03]黃文鍵(2.00)
第 19 週	Final Exam 2025-01-07(二),2025-01-10(五) 時數：[2025-01-07]黃文鍵(1.00)
第 19 週	Final Exam 2025-01-07(二),2025-01-10(五) 時數：[2025-01-10]黃文鍵(2.00)

教科書

Physical Cemistry 5e, K. J. Laidler, J. H. Meiser, and B. C. Sanctuary, Multi-Media Publicat, 2019

Office Hours

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