進階無機化學
Advanced Inorganic Chemistry
| 節 | 週三 |
|---|---|
2 09:00–09:50 | 進階無機化學 3 節連堂 |
3 10:10–11:00 | |
4 11:10–12:00 |
* 根據陽明交大上課時間表所列
授課教師：江建文 課程目標(中文) ： 1. 運用分子軌域理論、對稱性及配位場理論，描述過渡金屬錯合物的電子結構。 2. 解讀紫外-可見光、紅外線及電子順磁共振光譜數據，推導金屬錯合物的結構與鍵結。 3. 解釋有機金屬鍵結概念（18電子規則、配位數及π反鍵），並應用於常見配位基系統。 4. 分析配位基取代、電子轉移及基本有機金屬反應步驟的機制。 5. 描述並評估過渡金屬催化循環，包括交叉偶聯、氫化反應及C–H活化。 6. 連結生物無機化學原理與金屬蛋白及金屬酵素的功能。 7. 討論無機材料、奈米結構的最新進展及當代研究文獻。 8. 以英語清晰表達無機化學概念，並完成正式口頭報告。 *課程目標(英文) ： 1. Apply molecular orbital theory, symmetry, and ligand field theory to describe the electronic structure of transition-metal complexes. 2. Interpret UV-Vis, IR, and EPR spectroscopic data to deduce the structure and bonding of metal complexes. 3. Explain organometallic bonding concepts (18-electron rule, hapticity, and π-backbonding) and apply them to common ligand systems. 4. Analyze the mechanisms of ligand substitution, electron transfer, and fundamental organometallic reaction steps. 5. Describe and evaluate transition-metal catalytic cycles, including cross-coupling, hydrogenation, and C–H activation. 6. Relate principles of bioinorganic chemistry to the function of metalloproteins and metalloenzymes. 7. Discuss recent advances in inorganic materials, nanostructures, and the current research literature. 8. Communicate inorganic chemistry concepts clearly in English, including through a formal oral presentation.
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自編教材比例(%)：10 彈性教學說明(中文) ： 第9至15週之口頭報告主題暫定，可依課程進度及學術行事曆進行調整；任何更動將於課堂中公告。 *彈性教學說明(英文) ： The presentation topics for Weeks 9–15 are tentative and may be adjusted to accommodate the pace of the class and academic-calendar changes. Any modifications will be announced in class.
*評量配分比重(中文) ： 英文書面考試（期中考＋期末考）：50% 英文科學溝通（口頭報告與問答）：50% *評量配分比重(英文) ： Written Examinations in English (Midterm + Final): 50% Scientific Communication in English (Oral Presentation & Q&A): 50%
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| 週次 | 主題 |
|---|---|
| 第 1 週 | 課程簡介；回顧原子結構、週期趨勢、鍵結理論及酸鹼概念 Course introduction; review of atomic structure, periodic trends, bonding theories, and acid–base concepts |
| 第 2 週 | 分子軌域理論與分子對稱性；配位場理論與電子躍遷；過渡金屬錯合物光譜（UV-Vis、IR、EPR） Molecular orbital theory and molecular symmetry; ligand field theory and electronic transitions; spectroscopy of transition-metal complexes (UV-Vis, IR, EPR) |
| 第 3 週 | 有機金屬化學：18電子規則、配位性及常見配位基；金屬-配位基鍵結與π反鍵 Organometallic chemistry — 18-electron rule, hapticity, and common ligands; metal–ligand bonding and π-backbonding |
| 第 4 週 | 配位基分類（σ-給體、π-給體、π-受體）；螯合效應、齒數、兩性配位基及光譜化學序列 Ligand classification (σ-donors, π-donors, π-acceptors); chelate effect, denticity, ambidentate ligands, and the spectrochemical series |
| 第 5 週 | 配位錯合物反應機制；配位基取代（締合vs.解離）、反位效應及電子轉移反應；基本有機金屬反應（氧化加成、還原消去、插入及β-氫消除）Reaction mechanisms of coordination complexes; ligand substitution (associative vs. dissociative), the trans effect, and electron-transfer reactions; fundamental organometallic reactions (oxidative addition, reductive elimination, migratory insertion, β-hydride elimination) |
| 第 6 週 | 生物無機化學 II：氧氣傳輸、NO/CO鍵結及金屬酵素 Bioinorganic Chemistry II — oxygen transport, NO/CO binding, and metalloenzymes |
| 第 7 週 | 生物無機化學 I：金屬蛋白與電子傳遞；無機化學最新進展——研究論文討論Bioinorganic Chemistry I — metalloproteins and electron transfer; recent advances in inorganic chemistry (research article discussion) |
| 第 8 週 | 期中考 Midterm Examination |
| 第 9 週 | 學生口頭報告（有機金屬、均相催化、生物無機、無機材料等主題，各組輪流發表）Student oral presentations on selected topics (organometallic bonding, homogeneous catalysis, bioinorganic chemistry, inorganic materials, etc.) |
| 第 10 週 | 學生口頭報告（有機金屬、均相催化、生物無機、無機材料等主題，各組輪流發表）Student oral presentations on selected topics (organometallic bonding, homogeneous catalysis, bioinorganic chemistry, inorganic materials, etc.) |
| 第 11 週 | 學生口頭報告（有機金屬、均相催化、生物無機、無機材料等主題，各組輪流發表）Student oral presentations on selected topics (organometallic bonding, homogeneous catalysis, bioinorganic chemistry, inorganic materials, etc.) |
| 第 12 週 | 學生口頭報告（有機金屬、均相催化、生物無機、無機材料等主題，各組輪流發表）Student oral presentations on selected topics (organometallic bonding, homogeneous catalysis, bioinorganic chemistry, inorganic materials, etc.) |
| 第 13 週 | 學生口頭報告（有機金屬、均相催化、生物無機、無機材料等主題，各組輪流發表）Student oral presentations on selected topics (organometallic bonding, homogeneous catalysis, bioinorganic chemistry, inorganic materials, etc.) |
| 第 14 週 | 學生口頭報告（有機金屬、均相催化、生物無機、無機材料等主題，各組輪流發表）Student oral presentations on selected topics (organometallic bonding, homogeneous catalysis, bioinorganic chemistry, inorganic materials, etc.) |
| 第 15 週 | 學生口頭報告（有機金屬、均相催化、生物無機、無機材料等主題，各組輪流發表）Student oral presentations on selected topics (organometallic bonding, homogeneous catalysis, bioinorganic chemistry, inorganic materials, etc.) |
| 第 16 週 | 期末考Final Examination |
【主要教科書】 Miessler, Fischer, Tarr，《無機化學》，第5版，Pearson。 Housecroft, Sharpe，《無機化學》，第4版，Pearson。 【輔助參考書目】 Cotton, Wilkinson, Murillo, Bochmann，《高等無機化學》，第6版，Wiley。 Crabtree，《過渡金屬有機金屬化學》，Wiley。 Hartwig，《有機過渡金屬化學》，University Science Books。 Lippard, Berg，《生物無機化學原理》，University Science Books。 另由教師於課程中發放選定研究論文。 [Primary] Miessler, Fischer, and Tarr, Inorganic Chemistry, 5th ed., Pearson. Housecroft and Sharpe, Inorganic Chemistry, 4th ed., Pearson. [Supplementary] Cotton, Wilkinson, Murillo, and Bochmann, Advanced Inorganic Chemistry, 6th ed., Wiley. Crabtree, The Organometallic Chemistry of the Transition Metals, Wiley. Hartwig, Organotransition Metal Chemistry: From Bonding to Catalysis, University Science Books. Lippard and Berg, Principles of Bioinorganic Chemistry, University Science Books. Selected primary research articles distributed during the semester.
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